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To have a chance at snagging Lugia in the demo version, you must first snag the first 60. Then, go to the mountain with a Groundon statue and Lugia will fly there. You will them battle him. He is at level 50.
To get the Master Ball, see Professor Kranein the Pokemon HQ lab. He is in a room on the first floor. Talk to him and he will open up a passage in the floor. There is a chest in the room. Open it to find a Master Ball. You must have been to Citadark Isle at least once to get the Master Ball. It is best used on Lugia.
To catch Dragonite you must snag all the Shadow Pokemon (mostly caught by Miror B, if you did not catch them from the trainers). The Miror Radar will go off and it will say Miror B will be in Geteon Port. He will be on the lighthouse at the very top. Battle him and he will use a level 50 Dragonite. Be careful and save the game before you battle him.
Amulet Coin - Say "Yes" to every question.
White Herb - Say "Yes" to 2 questions.
Mental Herb - Say "Yes to 1 question.
Quick Claw - Say "No" to every question.
Early in the game, you can find Miror B. The first time you encounter him, he will ask to join his group. If you say yes, he will think that you are lying. Say no, and he will get mad. Either way, you will battle him. He has a Shadow Nosepass. The second time you encounter him, he is on this island. When you talk to him, he will battle you again. This time he has a Shadow Dragonite, and also the Shadow Nosepass if you did not catch it earlier.
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